SYNCHROTRON RADIATION SCIENCE
YOSHIHISA HARADA LAB.
INTRODUCTION OF LABORATORY
We can explore the origin of the electronic structure of materials responsible for their electronic, magnetic, and optical properties using extremely intense X-rays with a desired energy and high energy resolution that can be obtained using synchrotron radiation. Our home ground is SPring-8, one of the highest brilliant synchrotron facilities in the world; it is where we have developed noble and original spectroscopies for material science in ‘soft’ X-ray region in-between vacuum ultraviolet rays and X-rays. In particular, we are leading the world in soft X-ray emission spectroscopy, a kind of light scattering, promising for electronic structure analyses of liquids and operando spectroscopy of a variety of catalysts. Our studies include: *observation of elementary excitations (crystal field excitation, spinon, magnon, charge density wave, orbiton etc.) in strongly correlated materials like Mott insulators and noble high temperature superconductors *electronic structure analysis of aqueous solutions to study microheterogeneity and interaction at solid-liquid interfaces *development of in situ soft X-ray spectroscopy for surface reaction of fuel cell catalysts, electrochemical reaction, and photocatalytic reaction *electronic structure analysis of reaction center in metalloproteins *basic study on ultrahigh energy resolution optics for soft X-ray emission and time-resolved spectroscopy
高分子電解質ブラシの中に浸透した水( Confined water)。
軟X線非弾性散乱で捉えた常温の水(緑)、氷(青)と高分子電解質ポリマーブラシに浸透した水(赤)の比較。
MESSAGE
FROM INTERESTS IN LIGHT ITSELF TO ITS INTERACTION WITH MATTER; I BELIEVE RESEARCH QUALITY DEPENDS ON HOW IT CAN BROADEN ONE’S INTERESTS.
We recognize a material’s color by detecting a visible light that we call green, yellow or red in the case of a leaf, which depends on the absorption or transmission property of the light reflecting complex interaction between the light and the material. When a material is illuminated by a light called “soft X-ray”, we see another “color” that provides a lot of information about the origin of the electronic and magnetic property and local bond coordination, local symmetry and so on. We are currently developing soft X-ray emission spectroscopy, a tool to detect such soft X-ray “color” with an intense and well-organized (color, size, polarization, position, time-structure and so on) soft X-ray light source called synchrotron radiation. With only a slight advance in the sample handling, we can extend the target of this noble spectroscopy and obtain new information that cannot be made available by other methods. For example, pure liquid water, which is entirely transparent in the visible light region, looks inhomogeneous in terms of the energy distribution of valence electrons responsible for hydrogen bond formation when observed by soft X-rays. Four years ago, we reported the inhomogeneity of liquid water, which became a subject of discussion worldwide and is still much debated in water-related international conferences and on journal papers. Soft X-ray emission spectroscopy is such a powerful technique that provides us a chance to explore new fields.
keyword
RIXS / XAS / Acidic OER / Ruthenium based catalyst / Soft-XAS / HERFD-XAS / Operando measurement / CO2 reduction reaction / Cobalt phthalocyanine / In-situ measurement / Small-angle neutron scattering / Water-material interaction analysis / Movement of hydrosphere functional materials Analysis / Structural analysis of hydrosphere functional materials / Optimization of advanced measurement methods / Elucidation of the functional expression mechanism of hydrosphere functional materials / Shear flow field / Motion state of water / Secondary hydration sphere / Neutron reflectance / Neutron quasi-elastic scattering / Hydrogen Bonded structure / Water structure and motion / Terahertz spectroscopy / Neutron scattering / Synchrotron radiation infrared spectroscopy / Synchrotron radiation soft X-ray spectroscopy / MANGANESE CLUSTER / LIQUID CELL / SOFT X-RAY ABSORPTION / SOFT X-RAY EMISSION / Metalloprotein / Manganese Cluster / Solution cell / Soft X-ray absorption / Soft X-ray emission / Radiation, X-rays, particle beams / Radiation, X-rays, particle beams / Photophysical properties / Chemical physics
PROFILE : Professor Yoshihisa Harada
He graduated from the University of Tokyo and got a Ph.D. degree (2000) under the supervision of Professor Shik Shin. He was a fellow of Japan Society for the Promotion of Science (JSPS) and then moved to RIKEN/SPring-8 as a postdoctoral researcher (2000-2007). He was appointed as project lecturer (2007-2009) and project associate professor (2009-2011) at the University of Tokyo. He became Associate Professor at ISSP, the University of Tokyo in 2011 and was promoted to Professor in 2018.
STUDENT VOICE : AYAKO KAMEDA
Prof. Harada is at the forefront of soft x-ray research and is actively pioneering new research subjects. He is also keen to teach students, giving polite and thoughtful comments, and is always willing to help us with various consultations. Our laboratory’s characteristics are that it is located in a large synchrotron radiation facility, SPring-8, where we can conduct research surrounded by a lot of instrumentations and many researchers from various fields. Many of our members are overseas, and we enjoy our daily activities in this luxurious environment and global atmosphere (and nature!).
SOLID STATE PHYSICS AND CHEMISTRY
Knowing what your interests are and how you can expand your spectrum of interests from there.
This is a necessary quality for researchers.
Yoshihisa Harada Lab.,
Department Of Advanced Materials Science,
Graduate School of Frontier Sciences,
The University of Tokyo
Kashiwanoha 5-1-5,
Kashiwa,Chiba 277-8561, Japan
+81-791-58-0802-3966(Harima)
+81-4-7136-3401(Kashiwa)
harada@issp.u-tokyo.ac.jp
The Goal of Applied Physics
The goal of Applied Physics is to develop a stage = “new material” that can manipulate undeveloped degrees of freedom, to explore unknown phenomena created from that stage and to bring out excellent functions, and to bring out its excellent functions. The purpose is to contribute to the development of human society by elucidating the mechanisms and developing application fields for these phenomena and functions.
AMS (Advanced Materials Science)
Department Office
AMS (Advanced Materials Science),
Graduate School of Frontier Sciences,
The University of Tokyo
Kashiwanoha 5-1-5, Kashiwa, Chiba 277-8561, Japan
Email : ams-office(at)ams.k.u-tokyo.ac.jp
Please change (at) to @.